Issue 16, 2001

Tandem isomerisation–carbonylation catalysis: highly active palladium(ii) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

Abstract

Fast, selective conversion of internal olefins to linear esters is catalysed by Pd(II) complexes of chelating bis(phospha-adamantyl)diphosphines and the catalysis is acutely sensitive to the ligand backbone and even to the diastereomer used; the results are compared with those for the PBut2 analogue.

Article information

Article type
Communication
Submitted
25 Apr 2001
Accepted
11 Jun 2001
First published
23 Jul 2001

Chem. Commun., 2001, 1476-1477

Tandem isomerisation–carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

R. I. Pugh, E. Drent and P. G. Pringle, Chem. Commun., 2001, 1476 DOI: 10.1039/B103754B

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