In-situ planar chirality was induced in an achiral ligand by intramolecular π-stacking interactions upon complexation with silver(I) and crystallisation, to give a single-stranded helix with a nanoscale pitch which assembled into a three-dimensional network.
Formation of a single-stranded silver(I) helical-coordination polymer containing π-stacked planar chiral N4S2 ligands
P. L. Caradoc-Davies and L. R. Hanton, Chem. Commun., 2001, 1098 DOI: 10.1039/B101875M
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