Issue 12, 2001
From the journal:

Chemical Communications

Diphosphites as a promising new class of ligands in Pd-catalysed asymmetric allylic alkylation

Montserrat Diéguez,*a   Susanna Jansat,b   Montserrat Gomez,*b   Aurora Ruiz,a   Guillermo Mullera  and  Carmen Clavera  

* Corresponding authors

a Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Pl. Imperial Taraco 1, Tarragona, Spain.
E-mail: dieguez@quimica.urv.es

b Departament de Química Inorgànica, Universitat de Barcelona, Martí i Franquès, 1-11, Barcelona, Spain.
E-mail: montserrat.gomez@qi.ub.es

Abstract

A series of diphosphite ligands, derived from readily available D-(+)-glucose, have been used for the first time in the palladium-catalysed allylic alkylation reaction with high enantioselectivity (ee up to 95%) and activity in standard conditions.

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Article information

DOI
https://doi.org/10.1039/B101567M
Article type
Communication
Submitted
16 Feb 2001
Accepted
03 May 2001
First published
31 May 2001

Chem. Commun., 2001, 1132-1133

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Diphosphites as a promising new class of ligands in Pd-catalysed asymmetric allylic alkylation

M. Diéguez, S. Jansat, M. Gomez, A. Ruiz, G. Muller and C. Claver, Chem. Commun., 2001, 1132 DOI: 10.1039/B101567M

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