Issue 12, 2001
From the journal:

Chemical Communications

Theoretical study of triple bonds to germanium: relative stabilities of germanitriles and germaimines

Chin-Hung Lai,a   Ming-Der Su*b  and  San-Yan Chu*a  

* Corresponding authors

a Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan, R.O.C.

b School of Chemistry, Kaohsiung Medical University, Kaohsiung, Taiwan, R.O.C.
E-mail: ggs@chu1.chem.nthu.edu.tw

Abstract

Both B3LYP and CCSD(T) computational results suggest that fluorine substitution can dramatically stabilize FGe[triple bond, length half m-dash]N, with respect to Ge[double bond, length half m-dash]NF, both from a kinetic and from a thermodynamic viewpoint.

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Article information

DOI
https://doi.org/10.1039/B101459P
Article type
Communication
Submitted
14 Feb 2001
Accepted
18 Apr 2001
First published
31 May 2001

Chem. Commun., 2001, 1120-1121

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Theoretical study of triple bonds to germanium: relative stabilities of germanitriles and germaimines

C. Lai, M. Su and S. Chu, Chem. Commun., 2001, 1120 DOI: 10.1039/B101459P

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