Cooperative cation and anion coordination by a bifunctional imidophosphorane ligand framework; syntheses and structures of [LiCl{ButNHP)μ-NBut)2PNH(2-py)}3] and [{ButNP(μ-NBut)2PN(2-py)}Li2·{Li(ButN)2P}]

Andrew D. Bond; Emma L. Doyle; Sara J. Kidd; Anthony D. Woods; Dominic S. Wright

doi:10.1039/B010093P

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Cooperative cation and anion coordination by a bifunctional imidophosphorane ligand framework; syntheses and structures of [LiCl{Bu^tNHP)μ-NBu^t)₂PNH(2-py)}₃] and [{Bu^tNP(μ-NBu^t)₂PN(2-py)}Li₂·{Li(Bu^tN)₂P}] Electronic supplementary information (ESI) available: syntheses of 1 and 2. See http://www.rsc.org/suppdata/cc/b0/b010093p/

Andrew D. Bond,^a Emma L. Doyle,^a Sara J. Kidd,^a Anthony D. Woods^a and Dominic S. Wright*^a

Author affiliations

* Corresponding authors

^a Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: dsw1000@cus.cam.ac.uk

Abstract

The neutral ligand [Bu^tNHP(μ-NBu^t)₂PNH(2-py)] and its dilithiate [{Bu^tNP(μ-NBu^t)₂PN(2-py)}Li ₂] exhibit a parallel ability to coordinate cations and anions, as revealed in the structures of the tris-solvate [LiCl{Bu^tNHP(μ-NBu^t)₂PNH(2-py) }₃] 1 and the unusual co-complex [{Bu^tNP(μ-NBu^t)₂PN(2-py)}Li ₂·{Li(Bu^tN)₂P}] 2.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B010093P
Article type: Communication
Submitted: 18 Dec 2000
Accepted: 08 Mar 2001
First published: 03 Apr 2001

Download Citation

Chem. Commun., 2001, 777-778

Permissions

Request permissions

Cooperative cation and anion coordination by a bifunctional imidophosphorane ligand framework; syntheses and structures of [LiCl{Bu^tNHP)μ-NBu^t)₂PNH(2-py)}₃] and [{Bu^tNP(μ-NBu^t)₂PN(2-py)}Li₂·{Li(Bu^tN)₂P}]

A. D. Bond, E. L. Doyle, S. J. Kidd, A. D. Woods and D. S. Wright, Chem. Commun., 2001, 777 DOI: 10.1039/B010093P

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications