Frequency distributions of hydrogen bond trajectories for X–H⋯Ph interactions (X = O, N, C) need to be corrected for the finite area of the acceptor moiety and once this correction has been performed, it is seen that the donor groups have a distinct tendency to interact with the centroid of the aromatic ring.
Area correction of multi-atom–acceptor hydrogen bond frequency distributions
Z. Ciunik and G. R. Desiraju, Chem. Commun., 2001, 703 DOI: 10.1039/B009227B
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