Issue 4, 2001
From the journal:

Chemical Communications

Hydrolysis of phosphodiester with hydroxo- or carboxylate-bridged dinuclear Ni(ii) and Cu(ii) complexes

Kazuya Yamaguchi,*a   Fumio Akagi,a   Shuhei Fujinami,b   Masatatsu Suzuki,b   Mitsuhiko Shionoyac  and  Shinnichiro Suzukia  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka University, 1-16 Machikaneyama, Toyonaka, Osaka, Japan.
E-mail: kazu@ch.wani.osaka-u.ac.jp

b Department of Chemistry, Faculty of Science, Kanazawa University, Kakuma-machi, Kanazawa, Japan

c Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan

Abstract

A hydroxo- or carboxylate-bridged dinuclear Ni(II) complexes with N,N,N′,N′-tetrakis{(6-methyl-2-pyridyl)methyl }-1,3-diaminopropan-2-ol has been synthesized as models for Ni(II)-substituted phosphotriesterase, which are more active catalysts for hydrolysis of phosphodiester than the corresponding dinuclear Cu(II) and Zn(II) complexes.

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Article information

DOI
https://doi.org/10.1039/B008994J
Article type
Communication
Submitted
08 Nov 2000
Accepted
15 Jan 2001
First published
08 Feb 2001

Chem. Commun., 2001, 375-376

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Hydrolysis of phosphodiester with hydroxo- or carboxylate-bridged dinuclear Ni(II) and Cu(II) complexes

K. Yamaguchi, F. Akagi, S. Fujinami, M. Suzuki, M. Shionoya and S. Suzuki, Chem. Commun., 2001, 375 DOI: 10.1039/B008994J

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