Issue 1, 2001
From the journal:

Chemical Communications

Ferromagnetic interactions in the first dicubane-type complex involving cyanate ligand: [Co4(dpk-OH)2(dpk-OMe)2(NCO)4]

M. Gotzone Barandika,a   Zurine Serna,b   Roberto Cortés,*a   Luis Lezama,b   M. Karmele Urtiaga,c   M. Isabel Arriortuac  and  Teófilo Rojo*b  

* Corresponding authors

a Departamento de Química Inorgánica, Fac. Farmacia, UPV/EHU, Aptdo. 450, Vitoria, Spain.
E-mail: qipcomor@lg.ehu.es

b Departamento de Química Inorgánica, Fac. Ciencias, UPV/EHU, Aptdo. 644, Bilbao, Spain

c Departamento de Mineralogía-Petrología, Fac. Ciencias, UPV/EHU, Aptdo. 644, Bilbao, Spain

Abstract

The ligands cyanate and di-2-pyridyl ketone (dpk) are used to construct a tetranuclear cobalt(II) complex involving μ1,1-cyanate bridges: [Co4(dpk-OH)2(dpk-OMe)2(NCO)4], which shows a dicubane-type structure, with two missing vertices, and having ferromagnetic interactions.

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Article information

DOI
https://doi.org/10.1039/B008256M
Article type
Communication
Submitted
12 Oct 2000
Accepted
14 Nov 2000
First published
15 Dec 2000

Chem. Commun., 2001, 45-46

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Ferromagnetic interactions in the first dicubane-type complex involving cyanate ligand: [Co4(dpk-OH)2(dpk-OMe)2(NCO)4]

M. G. Barandika, Z. Serna, R. Cortés, L. Lezama, M. K. Urtiaga, M. I. Arriortua and T. Rojo, Chem. Commun., 2001, 45 DOI: 10.1039/B008256M

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