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Issue 2, 2001
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Heterobimetallic intermediates in alkene insertion reactions into a Pd–acetyl bondElectronic supplementary information (ESI) available: Experimental. See http://www.rsc.org/suppdata/cc/b0/b007171o/

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Abstract

The reactivity of diphosphine-bridged heterobimetallic Fe–Pd alkyl complexes was evaluated for the insertion of CO, isonitriles, ethylene, methyl acrylate and norbornadienes and the crystal structures of the precursor alkyl complex, the iminoacyl derivative and the five-membered ring complex resulting from ethylene insertion into the palladium–acyl bond are reported.

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Submitted
05 Sep 2000
Accepted
12 Dec 2000
First published
15 Jan 2001

Chem. Commun., 2001, 211-212
Article type
Communication

Heterobimetallic intermediates in alkene insertion reactions into a Pd–acetyl bond

P. Braunstein, J. Durand, M. Knorr and C. Strohmann, Chem. Commun., 2001, 211
DOI: 10.1039/B007171O

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