Issue 4, 2001
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Isolation and characterisation of bis(oxahomo)fullerene derivatives of C60F18

Olga V. Boltalina,a   Benoît de La Vaissière,b   Andrei Yu. Lukonin,a   Patrick W. Fowler,b   Ala’a K. Abdul-Sada,d   Joan M. Streetc  and  Roger Taylor*d  

* Corresponding authors

a Chemistry Department, Moscow University, Moscow, Russia

b School of Chemistry, University of Exeter, Stocker Road, Exeter, UK

c Chemistry Department, The University, Southampton, UK

d The Chemistry Laboratory, CPES School, Sussex University, Brighton, UK

Abstract

From the products of the reaction of [60]fullerene with K2PtF6 under vacuum at 465 °C we have isolated seven isomers of C60F18O2, and characterized them by EI mass spectrometry, IR and 19F NMR spectroscopy (both 1 D and 2 D). Comparison with data for mono-oxides and the observed lack of connectivity between the fluorines attached to carbons adjacent to oxygen, indicate that these compounds are diethers with oxygen inserted between fluorinated carbons. Structures proposed on the basis of the NMR spectra and semiempirical calculations are found to be consistent with HPLC retention times.

Graphical abstract: Isolation and characterisation of bis(oxahomo)fullerene derivatives of C60F18

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Article information

DOI
https://doi.org/10.1039/B007935I
Article type
Paper
Submitted
02 Oct 2000
Accepted
08 Jan 2001
First published
19 Feb 2001

J. Chem. Soc., Perkin Trans. 2, 2001, 550-556

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Isolation and characterisation of bis(oxahomo)fullerene derivatives of C60F18

O. V. Boltalina, B. de La Vaissière, A. Yu. Lukonin, P. W. Fowler, A. K. Abdul-Sada, J. M. Street and R. Taylor, J. Chem. Soc., Perkin Trans. 2, 2001, 550 DOI: 10.1039/B007935I

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