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Issue 15, 2001
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Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru– and Os–polypyridine termini

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Abstract

The extent of photoinduced energy-transfer between [Ru(bipy)3]2+ and [Os(bipy)3]2+ units attached to either end of a deca(oxoethylene) 33-atom chain can be used to show how the distribution of end-to-end distances in the ensemble of conformations changes in different solvents.

Graphical abstract: Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru– and Os–polypyridine termini

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Article information


Submitted
29 May 2001
Accepted
22 Jun 2001
First published
06 Jul 2001

J. Chem. Soc., Dalton Trans., 2001, 2228-2231
Article type
Communication

Folding of a poly(oxyethylene) chain as probed by photoinduced energy transfer between Ru– and Os–polypyridine termini

S. J. A. Pope, C. R. Rice, M. D. Ward, A. F. Morales, G. Accorsi, N. Armaroli and F. Barigelletti, J. Chem. Soc., Dalton Trans., 2001, 2228
DOI: 10.1039/B104637N

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