Unexpected formation of gallium–gallium single bonds by irradiation of the hydride [(Me3C)2GaH]3
Abstract
Di(tert-butyl)gallium hydride 1 dismutates partially in solution forming tri(tert-butyl)gallium 2 and the sesquihydride [(Me3C)2GaH]2[H2GaCMe3]2 (3). The loss of