Issue 22, 2001
From the journal:

Chemical Communications

Reduction of tris(benzene-1,2-dithiolate)molybdenum(vi) by hydroxide ions in dry tetrahydrofuran solution

Antonio Cervilla,*a   Francisco Pérez-Plab  and  Elisa Llopisa  

* Corresponding authors

a Departamento de Química Inorgànica, ICMUV, PO Box 2085, Polígono La Coma, Paterna, Valencia, Spain.
E-mail: Antonio Cervilla@.uv.es;
Fax: 34963983633

b Departamento de Química-Física, Universidad de Valencia, Dr. Moliner 50, Valencia, Spain

Abstract

Tris(benzene-1,2-dithiolate)molybdenum(VI) reacts rapidly and quantitatively with tetrabutylammonium hydroxide to yield the corresponding Mo(V) and Mo(IV) complexes and hydrogen peroxide; the reaction has been executed in dry tetrahydrofuran where the reaction rate shows a fair dependence on complex and OH− concentrations.

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Article information

DOI
https://doi.org/10.1039/B106123M
Article type
Communication
Submitted
10 Jul 2001
Accepted
04 Oct 2001
First published
25 Oct 2001

Chem. Commun., 2001, 2332-2333

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Reduction of tris(benzene-1,2-dithiolate)molybdenum(VI) by hydroxide ions in dry tetrahydrofuran solution

A. Cervilla, F. Pérez-Pla and E. Llopis, Chem. Commun., 2001, 2332 DOI: 10.1039/B106123M

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