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Issue 16, 2001
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Tandem isomerisation–carbonylation catalysis: highly active palladium(ii) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

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Abstract

Fast, selective conversion of internal olefins to linear esters is catalysed by Pd(II) complexes of chelating bis(phospha-adamantyl)diphosphines and the catalysis is acutely sensitive to the ligand backbone and even to the diastereomer used; the results are compared with those for the PBut2 analogue.

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Article information


Submitted
25 Apr 2001
Accepted
11 Jun 2001
First published
23 Jul 2001

Chem. Commun., 2001, 1476-1477
Article type
Communication

Tandem isomerisation–carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

R. I. Pugh, E. Drent and P. G. Pringle, Chem. Commun., 2001, 1476
DOI: 10.1039/B103754B

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