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Issue 2, 2001
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A remarkable Cr(iii) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

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Abstract

In addition to a quadruply bonded dichromium(II,II) compound of unusual structure, we have obtained a dinuclear, antiferromagnetically coupled, CrIII complex [Cr2(μ-OMe)23-N,C,N′ -H2DpyF)2Cl2·MeOH, H2DpyF = CH(NH-pyridyl)2] containing a transformed formamidinate group in which the central carbon atom has changed from sp2 to sp3 hybridization and Cr–C bonds have been formed; details of the crystal structure of the organometallic compound are given here.

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Article information


Submitted
11 Aug 2000
Accepted
06 Dec 2000
First published
09 Jan 2001

Chem. Commun., 2001, 205-206
Article type
Communication

A remarkable Cr(III) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion

R. Clérac, F. A. Cotton, C. A. Murillo and X. Wang, Chem. Commun., 2001, 205
DOI: 10.1039/B007813L

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