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Issue 15, 2001
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TEMPO: a novel chameleonic ligand for s-block metal amide chemistryElectronic supplementary information (ESI) available: experimental, synthesis and characterisation data. See http://www.rsc.org/suppdata/cc/b1/b104937m/

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Abstract

The first structurally characterised examples of the nitroxide TEMPO acting as a ligand towards Li, Na or Mg are described, through a series of hexamethyldisilazide complexes which reveals a remarkable breadth of variety in structure and in the mode of ligation.

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Article information


Submitted
05 Jun 2001
Accepted
22 Jun 2001
First published
12 Jul 2001

Chem. Commun., 2001, 1400-1401
Article type
Communication

TEMPO: a novel chameleonic ligand for s-block metal amide chemistry

G. C. Forbes, A. R. Kennedy, R. E. Mulvey and P. J. A. Rodger, Chem. Commun., 2001, 1400
DOI: 10.1039/B104937M

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