Konstantin N. Gavrilov and Aleksei I. Polosukhin
Russ. Chem. Rev., 2000,69, 661-682
DOI:
10.1070/RC2000v069n08ABEH000559,
Paper
Published data on the synthesis of rhodium and palladium complexes with optically active P,N-bidentate ligands and their applications in homogeneous asymmetric catalysis are summarised and discussed. The effect of the nature of the P,N-bidentate compounds on the structure of the metal complexes and on enantioselectivity in catalysis is examined. Allylic substitution, cross-coupling, hydroboration and hydrosilylation catalysed by Rh or Pd complexes with optically active P,N-bidentate ligands are considered. The prospects for the development of this field of chemistry are demonstrated. The bibliography includes 186 references.