Issue 3, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Novel azacrown ether-containing spiro[indoline-2,3′-naphthoxazines]: design, synthesis and cation-dependent photochromism

Olga A. Fedorova,a   Sergey P. Gromov,a   Yulia V. Pershina,a   Sergey S. Sergeev,a   Yuri P. Strokach,a   Valeri A. Barachevsky,a   Michael V. Alfimov,a   Gérard Pèpe,b   André Samat*b  and  Robert Guglielmettib  

* Corresponding authors

a Photochemistry Center, Russian Academy of Sciences, Novatorov str., 7a, Moscow, Russia

b Université de la Méditerranée, Faculté des Sciences de Luminy, ESA CNRS 6114, Case 901, Marseille, Cedex 9, France

Abstract

Novel spironaphthoxazine compounds with an aza-15-crown-5 ether fragment at position 5′ or 9′ of the naphthalene ring were synthesised. Spectrokinetic measurements showed the occurrence of two competing formation processes for complexation with alkaline earth or rare earth metal cations. A comparative study of the prepared compounds demonstrated the role of molecular design and the metal cation nature in the cation-dependent photoinduced transformation of spiro[indoline-naphthoxazines].

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Article information

DOI
https://doi.org/10.1039/A905671H
Article type
Paper
Submitted
13 Jul 1999
Accepted
25 Nov 1999
First published
08 Feb 2000

J. Chem. Soc., Perkin Trans. 2, 2000, 563-570

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Novel azacrown ether-containing spiro[indoline-2,3′-naphthoxazines]: design, synthesis and cation-dependent photochromism

O. A. Fedorova, S. P. Gromov, Y. V. Pershina, S. S. Sergeev, Y. P. Strokach, V. A. Barachevsky, M. V. Alfimov, G. Pèpe, A. Samat and R. Guglielmetti, J. Chem. Soc., Perkin Trans. 2, 2000, 563 DOI: 10.1039/A905671H

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