Issue 13, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Stereoselective synthesis of trans-2,6-diaryl-4-piperidones by using benzaldiminetricarbonylchromium derivatives

Kaori Ishimaru*a  and  Takakazu Kojimaa  

* Corresponding authors

a Department of Chemistry, The National Defense Academy, 1-10-20 Hashirimizu, Yokosuka, Japan

Abstract

Stereoselective synthesis of trans-2,6-diaryl-4-piperidones has been carried out by cycloaddition of benzaldiminetricarbonylchromium derivatives 1 with 2-silyloxybuta-1,3-diene in the presence of trimethylsilyl triflate as a Lewis acid. The tricarbonylchromium moiety played an important role in increasing the stereoselectivities of the products.

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Article information

DOI
https://doi.org/10.1039/B001540G
Article type
Paper
Submitted
24 Feb 2000
Accepted
09 May 2000
First published
09 Jun 2000

J. Chem. Soc., Perkin Trans. 1, 2000, 2105-2108

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Stereoselective synthesis of trans-2,6-diaryl-4-piperidones by using benzaldiminetricarbonylchromium derivatives

K. Ishimaru and T. Kojima, J. Chem. Soc., Perkin Trans. 1, 2000, 2105 DOI: 10.1039/B001540G

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