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Issue 12, 2000
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Concave reagents part 33: transition metal complexes of 1,10-phenanthroline bridged calix[6]arenes

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Abstract

1,10-Phenanthroline bridged calix[6]arenes 1a and 1b have been synthesized and metal salt complexes with Cu+, Cu2+, Co2+, Ni2+ and Eu3+ have been isolated. In contrast to the concave 1,10-phenanthrolines 2, which only form 1:1 complexes with metal salts, 1 also forms 2:1 complexes with Cu2+, Co2+ and Ni2+. Only Cu+ forms 1:1 complexes exclusively.

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Article information


Submitted
16 Aug 2000
Accepted
26 Oct 2000
First published
21 Nov 2000

New J. Chem., 2000,24, 935-938
Article type
Letter

Concave reagents part 33: transition metal complexes of 1,10-phenanthroline bridged calix[6]arenes

F. Löffler, U. Lüning and G. Gohar, New J. Chem., 2000, 24, 935
DOI: 10.1039/B006826H

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