Issue 10, 2000
From the journal:

New Journal of Chemistry

First assembly of copper(I) naphthyridine-based helicates

Raymond Ziessel,*a   Anthony Harriman,*b   Abdelkrim El-ghayoury,a   Laurent Douce,a   Emmanuelle Leize,c   Hélène Nierengartenc  and  Alain Van Dorsselaerc  

* Corresponding authors

a Laboratoire de Chimie, d'Electronique et de Photonique Moléculaires (CNRS ESA 7008), Ecole Européenne de Chimie, Polymères et Matériaux, Uniersité Louis Pasteur, 25 rue Becquerel, Strasbourg cedex 2, France
E-mail: ziessel@chimie.u-strasbg.fr

b Department of Chemistry, Uniersity of Newcastle, Newcastle-upon-Tyne, UK

c Laboratoire de Spectrométrie de Masse Bio-organique (CNRS URA 21), ECPM, 25 rue Becquerel, Strasbourg cedex 2, France
E-mail: vanders@chimie.u-strasbg.fr

Abstract

Copper(I) binds to 2,7-diimino-1,8-naphthyridine in solution to form a mixture of equilibrating mono- and polynuclear complexes, as identified by electrospray MS and monitored by UV-visible spectrophotometric titrations, including a binuclear metallo-helicate for which X-ray data are available but whose formation does not require cooperative associations.

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Article information

DOI
https://doi.org/10.1039/B003342L
Article type
Letter
Submitted
21 Apr 2000
Accepted
04 Aug 2000
First published
20 Sep 2000

New J. Chem., 2000,24, 729-732

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First assembly of copper(I) naphthyridine-based helicates

R. Ziessel, A. Harriman, A. El-ghayoury, L. Douce, E. Leize, H. Nierengarten and A. Van Dorsselaer, New J. Chem., 2000, 24, 729 DOI: 10.1039/B003342L

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