Issue 10, 2000
From the journal:

New Journal of Chemistry

Triphenylmethyl tris(p-methoxyphenyl)phosphonium cation: a structurally characterized phosphonium analog of hexaphenylethane

Xinggao Fang,a   Brian L. Scott,a   Kevin D. John,a   Gregory J. Kubas*a  and  John G. Watkina  

* Corresponding authors

a Chemical Science and Technology Diision, MS J514, Los Alamos National Laboratory, Los Alamos, NM, USA
E-mail: kubas@lanl.gov

Abstract

Reaction of tris(p-methoxyphenyl)phosphine with [Ph3C][B(ArF)4] [ArF=3,5-(CF3)2C6H3] afforded [Ph3CP(4-OMeC6H4)3][B(ArF)4], a structural analog of hexaphenylethane, which shows a very long P–C distance [1.931(3) Å] in the solid state, indicating a strong steric repulsive interaction between the two parts of the phosphonium cation.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B003233F
Article type
Paper
Submitted
19 Apr 2000
Accepted
12 Jul 2000
First published
08 Sep 2000

New J. Chem., 2000,24, 831-833

Permissions

Request permissions

Triphenylmethyl tris(p-methoxyphenyl)phosphonium cation: a structurally characterized phosphonium analog of hexaphenylethane

X. Fang, B. L. Scott, K. D. John, G. J. Kubas and J. G. Watkin, New J. Chem., 2000, 24, 831 DOI: 10.1039/B003233F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements