Reactions of Ti(Ind)Cl3, 1, with LiNMe2 afforded the corresponding titanium indenyldimethylamido complexes Ti(Ind)(NMe2)Cl2, 2, Ti(Ind)(NMe2)2Cl, 3, and Ti(Ind)(NMe2)3, 4, depending on the reaction conditions. Treatment of 2 and 3 with LiMe yielded Ti(Ind)(NMe2)Me2, 5, and Ti(Ind)(NMe2)2Me, 6, respectively. Chloride metathesis reactions of Ti(Ind)(NMe2)2Cl with Me3SiCH2MgCl, LiCCPh and LiCCSiMe3 gave Ti(Ind)(NMe2)2(CH2SiMe3), 7, Ti(Ind)(NMe2)2(CCPh), 8 and Ti(Ind)(NMe2)2(CCSiMe3), 9. The solid-state molecular structure of 2 was determined. 1H and 13C NMR data and DFT calculations (full geometry optimisations) showed that the indenyl ring remains approximately planar and exhibits an η5 co-ordination mode in all the complexes. The amido groups have a preference for binding in the way that favours π bonding to the titanium. Even in the trisamido complex the indenyl remains η5, π bonding to the ring being preferred to that from the amides.