Issue 17, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Highly stable copper(I)-olefin coordination polymers capable of co-existing with water and acid

Jing Zhang,,a   Ren-Gen Xiong,*a   Jing-Lin Zuo,a   Chi-Ming Cheb  and  Xiao-Zeng You*a  

* Corresponding authors

a Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P. R. China
E-mail: xyz@netra.nju.edu.cn
Fax: (+86) 25 3314502

b Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong

Abstract

Under solvothermal conditions, the reactions of trans-3-(4-pyridyl)acrylic acid (4-HPYA) and 1,10-phenanthroline (phen), and trans-3-(3-pyridyl)acrylic acid (3-HPYA) and 2,2′-bipyridine (2,2′-bpy) with Cu(MeCN)4BF4 give rise to two unprecedented stable copper(I)–olefin coordination polymers, {[(phen)(4-HPYA)Cu(I)](BF4)}n (1) and {[(2,2′-bpy)(3-HPYA)Cu(I)](BF4)·H2O}n (2), respectively.

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Article information

DOI
https://doi.org/10.1039/B005101M
Article type
Communication
Submitted
26 Jun 2000
Accepted
28 Jul 2000
First published
14 Aug 2000

J. Chem. Soc., Dalton Trans., 2000, 2898-2900

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Highly stable copper(I)-olefin coordination polymers capable of co-existing with water and acid

J. Zhang,, R. Xiong, J. Zuo, C. Che and X. You, J. Chem. Soc., Dalton Trans., 2000, 2898 DOI: 10.1039/B005101M

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