Structural characterisation of basic zinc O,O′-dialkyl dithiophosphosphate and two isomeric examples of zinc monothiophosphates
Abstract
The crystal structure of basic Zn4O[S2P(OBui)2]6 revealed a Zn4O core. Two examples of zinc monothiophosphates, Zn4[O(S)P(OPh)2]6O and Zn4[O(S)P(OMe)2]6O, have also been synthesized and structurally characterised. These systems also contain a Zn4O core but display an interesting isomerism as a consequence of the unsymmetrical O,S donor