Fragmentation pathways of [Re2(μ-OR)3(CO)6]− (R = H, Me) and ligand exchange reactions with oxygen donor ligands, investigated by electrospray mass spectrometry
Probing the chemistry of the dinuclear rhenium carbonyl complexes [Re2(μ-OR)3(CO)6]− (R = H or Me) by electrospray mass spectrometry. Part 1.Electronic supplementary (ESI) available: ESMS data for the complexes [Re2(μ-OR)2(μ-dppf)(CO)6] (R = H or Me). See http://www.rsc.org/suppdata/dt/b0/b003893h/
Abstract
The rhenium )(CO)6] [R = H or Me; dppf = 1,1′-bis(diphenylphosphino)ferrocene] undergo substantial