Insights into the elimination of HCHO from the clusters [Mn(CO)m(COOMe)]− (Mn = Ru6C, m = 16; Mn = Rh6, m = 15) provided by electrospray mass spectrometry

Paul J. Dyson; Neil Feeder; Brian F. G. Johnson; J. Scott McIndoe; Patrick R. R. Langridge-Smith

doi:10.1039/B002978P

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Insights into the elimination of HCHO from the clusters [M_n(CO)_m(COOMe)]⁻ (M_n = Ru₆C, m = 16; M_n = Rh₆, m = 15) provided by electrospray mass spectrometry†

Paul J. Dyson,^a Neil Feeder,^b Brian F. G. Johnson,^b J. Scott McIndoe^b and Patrick R. R. Langridge-Smith^c

Author affiliations

^a Department of Chemistry, The University of York, Heslington, York, UK

^b Department of Chemistry, The University of Cambridge, Lensfield Road, Cambridge, UK
E-mail: jsm43@cam.ac.uk

^c Department of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, UK

Abstract

Loss of formaldehyde in the electrospray ionisation fragmentation process of methoxylated hexanuclear carbonyl clusters can be correlated to their macroscopic chemical properties.

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Article information

DOI: https://doi.org/10.1039/B002978P
Article type: Communication
Submitted: 13 Apr 2000
Accepted: 17 May 2000
First published: 26 May 2000

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J. Chem. Soc., Dalton Trans., 2000, 1813-1815

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Insights into the elimination of HCHO from the clusters [M_n(CO)_m(COOMe)]⁻ (M_n = Ru₆C, m = 16; M_n = Rh₆, m = 15) provided by electrospray mass spectrometry

P. J. Dyson, N. Feeder, B. F. G. Johnson, J. S. McIndoe and P. R. R. Langridge-Smith, J. Chem. Soc., Dalton Trans., 2000, 1813 DOI: 10.1039/B002978P

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Journal of the Chemical Society, Dalton Transactions