Issue 13, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

First single-crystal X-ray diffraction study of a lanthanide tricarbonate complex: [Co(NH3)6][Sm(CO3)3(H2O)]·4H2O

David L. Clark,a   Robert J. Donohoe,b   John C. Gordon,*c   Pamela L. Gordon,d   D. Webster Keogh,*d   Brian L. Scott,e   C. Drew Taitd  and  John G. Watkin*e  

* Corresponding authors

a Glenn T. Seaborg Institute for Transactinium Science, Nuclear Materials Technology (NMT-DO, Mail Stop E500) Division, Los Alamos National Laboratory, Los Alamos, New Mexico, USA

b Biosciences (B-2, Mail Stop J586) Division, Los Alamos National Laboratory, Los Alamos, New Mexico, USA

c Nuclear Materials Technology (NMT-DO, Mail Stop J514) Division, Los Alamos National Laboratory, Los Alamos, New Mexico, USA

d Chemical Science and Technology (CST-18, Mail Stop G739) Division, Los Alamos National Laboratory, Los Alamos, New Mexico, USA

e Chemical Science and Technology (CST-18, Mail Stop J514) Division, Los Alamos National Laboratory, Los Alamos, New Mexico, USA

Abstract

The first single-crystal X-ray diffraction study of a lanthanide tricarbonate complex, namely [Co(NH3)6][Sm(CO3)3(H2O)]·4H2O, is reported and reveals a zigzag chain structure of 9-coordinate samarium metal centers bridged by μ-η2∶η1 carbonate ligands.

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Article information

DOI
https://doi.org/10.1039/B000778L
Article type
Communication
Submitted
24 Jan 2000
Accepted
24 Apr 2000
First published
06 Jun 2000

J. Chem. Soc., Dalton Trans., 2000, 1975-1977

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First single-crystal X-ray diffraction study of a lanthanide tricarbonate complex: [Co(NH3)6][Sm(CO3)3(H2O)]·4H2O

D. L. Clark, R. J. Donohoe, J. C. Gordon, P. L. Gordon, D. W. Keogh, B. L. Scott, C. D. Tait and J. G. Watkin, J. Chem. Soc., Dalton Trans., 2000, 1975 DOI: 10.1039/B000778L

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