Syntheses, crystal structures and non-linear optical properties of two novel windmill-shaped clusters: [M2Pd4S8(dppm)2]·4DMF (M = W or Mo)
Abstract
Novel cluster compounds [M2Pd4S8(dppm)2]·4DMF (M = W 1 or Mo 2) were synthesized by the reaction of [NEt4]2[MS4] and [Pd(dppm)Cl2] (dppm = Ph2PCH2PPh2) in CH2Cl2 and CH3CN, and their crystal structures have been characterized by