The photodissociation mechanism of perfluoroazooctane was investigated using a matrix isolation technique on the basis of IR and EPR spectra and MO calculation. The detection and identification of perfluorooctyl diazenyl radical show that it is a feasible photolytic intermediate of the decomposition of perfluoroazooctane.
T. Nakamura, T. Ohana and Y. Koga, Phys. Chem. Chem. Phys., 2000, 2, 2535 DOI: 10.1039/B000851F
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