Design, synthesis and structural investigation of a 2-D coordination network based on the self-assembly of the tetracarboxylate derivative of tetrathiacalix[4]arene and
Abstract
The fully deprotonated tetrathiacalix[4]arene
14− in 1,3-alternate conformation and bearing four
carboxylate units was shown to act as a tecton leading, in the presence of
Ag+