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Issue 22, 2000
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Design, synthesis and structural investigation of a 2-D coordination network based on the self-assembly of the tetracarboxylate derivative of tetrathiacalix[4]arene and

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Abstract

The fully deprotonated tetrathiacalix[4]arene 14− in 1,3-alternate conformation and bearing four carboxylate units was shown to act as a tecton leading, in the presence of Ag+ cation, to a 2-D coordination network in the crystalline phase which can be described as discrete binuclear [14−, (Ag+)2]2− complexes interconnected by Ag+ cations.

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Publication details

The article was received on 25 Sep 2000, accepted on 05 Oct 2000 and first published on 01 Nov 2000


Article type: Communication
DOI: 10.1039/B007761P
Chem. Commun., 2000, 2219-2220

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    Design, synthesis and structural investigation of a 2-D coordination network based on the self-assembly of the tetracarboxylate derivative of tetrathiacalix[4]arene and silver cation

    H. Akdas, E. Graf, M. W. Hosseini, A. De Cian and J. McB. Harrowfield, Chem. Commun., 2000, 2219
    DOI: 10.1039/B007761P

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