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Issue 22, 2000
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Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes

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Abstract

The title reaction is applied to square-planar rhodium and platinum complexes with trans PPh2(CH2)6CH[double bond, length half m-dash]CH2 ligands, and square-planar platinum or octahedral tungsten complexes with trans or facial PPh[(CH2)6CH[double bond, length half m-dash]CH2]2 ligands. Ring-closing (poly)macrocyclizations occur.

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Publication details

The article was received on 12 Sep 2000, accepted on 02 Oct 2000 and first published on 06 Nov 2000


Article type: Communication
DOI: 10.1039/B007405P
Chem. Commun., 2000, 2261-2262

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    Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes

    E. B. Bauer, J. Ruwwe, J. M. Martín-Alvarez, T. B. Peters, J. C. Bohling, F. A. Hampel, S. Szafert, T. Lis and J. A. Gladysz, Chem. Commun., 2000, 2261
    DOI: 10.1039/B007405P

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