Issue 22, 2000
From the journal:

Chemical Communications

Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes

Eike B. Bauer,a   Johannes Ruwwe,a   José Miguel Martín-Alvarez,b   Thomas B. Peters,b   James C. Bohling,b   Frank A. Hampel,a   Slawomir Szafert,a   Tadeusz Lisc  and  J. A. Gladysz*a  

* Corresponding authors

a Institut für Organische Chemie, Friedrich-Alexander Universität Erlangen-Nürnberg, Henkestrasse 42, 91054 Erlangen, Germany.
E-mail: john.gladysz@organik.uni-erlangen.de

b Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, USA

c Department of Chemistry, University of Wroclaw, F. Joliot-Curie 14, 50-383 Wroclaw, Poland

Abstract

The title reaction is applied to square-planar rhodium and platinum complexes with trans PPh2(CH2)6CH[double bond, length half m-dash]CH2 ligands, and square-planar platinum or octahedral tungsten complexes with trans or facial PPh[(CH2)6CH[double bond, length half m-dash]CH2]2 ligands. Ring-closing (poly)macrocyclizations occur.

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Article information

DOI
https://doi.org/10.1039/B007405P
Article type
Communication
Submitted
12 Sep 2000
Accepted
02 Oct 2000
First published
06 Nov 2000

Chem. Commun., 2000, 2261-2262

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Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes

E. B. Bauer, J. Ruwwe, J. M. Martín-Alvarez, T. B. Peters, J. C. Bohling, F. A. Hampel, S. Szafert, T. Lis and J. A. Gladysz, Chem. Commun., 2000, 2261 DOI: 10.1039/B007405P

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