Issue 21, 2000
From the journal:

Chemical Communications

Enantiopure arene dioxides: chemoenzymatic synthesis and application in the production of trans-3,4-dihydrodiols

Derek R. Boyd,*a   Narain D. Sharma,a   Colin R. O’Dowda  and  Francis Hempenstalla  

* Corresponding authors

a School of Chemistry, The Queen’s University of Belfast, Belfast, UK

Abstract

Enantiopure syn- and anti-arene dioxides are synthesised from cis-dihydrodiol metabolites; anti-benzene dioxides are reduced to enantiopure trans-3,4-dihydrodiols while syn-benzene dioxides racemise thermally via 1,4-dioxocins.

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Article information

DOI
https://doi.org/10.1039/B006837N
Article type
Communication
Submitted
21 Aug 2000
Accepted
27 Sep 2000
First published
19 Oct 2000

Chem. Commun., 2000, 2151-2152

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Enantiopure arene dioxides: chemoenzymatic synthesis and application in the production of trans-3,4-dihydrodiols

D. R. Boyd, N. D. Sharma, C. R. O’Dowd and F. Hempenstall, Chem. Commun., 2000, 2151 DOI: 10.1039/B006837N

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