Issue 24, 2000

A third isolated oxidation state for the Mn12 family of single-molecule magnets

Abstract

Dianionic members of the Mn12 family of single-molecule magnets have been prepared by two-electron reduction of the neutral cluster; the [PPh4]2[Mn12O12(O2C CHCl2)16- (H2O)4] representative has been shown to possess an S = 10 ground state and to exhibit out-of-phase ac susceptibility signals diagnostic of single-molecule magnetism behavior.

Supplementary files

Article information

Article type
Communication
Submitted
27 Jul 2000
Accepted
13 Oct 2000
First published
22 Nov 2000

Chem. Commun., 2000, 2417-2418

A third isolated oxidation state for the Mn12 family of single-molecule magnets

M. Soler, S. K. Chandra, D. Ruiz, E. R. Davidson, D. N. Hendrickson and G. Christou, Chem. Commun., 2000, 2417 DOI: 10.1039/B006519F

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