Issue 19, 2000
From the journal:

Chemical Communications

A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalystElectronic supplementary information (ESI) available: 1H, 13C and 31P NMR spectroscopic data for the ferrocenyl precursor 2, the anchored heterogeneous catalyst and the silsesquioxane-bound homogeneous catalyst. See http://www.rsc.org/suppdata/cc/b0/b005689h/

Stuart A. Raynor,a   John Meurig Thomas,*a   Robert Raja,a   Brian F. G. Johnson,*b   Robert G. Bellb  and  Mike D. Mantlec  

* Corresponding authors

a Davy-Faraday Research Laboratory, The Royal Institution of Great Britain, 21 Albemarle Street, London, UK
E-mail: jmt@ri.ac.uk

b University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge, UK

c Department of Chemical Engineering, The University of Cambridge, New Museum Site, Cambridge, UK

Abstract

A chiral catalyst derived from 1,1′-bis(diphenylphosphino)ferrocene and anchored within MCM-41 displays remarkable increases in both enantioselectivity and activity, in the hydrogenation of ethyl nicotinate to ethyl nipecotinate, when compared to an analogous homogeneous model compound.

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Article information

DOI
https://doi.org/10.1039/B005689H
Article type
Communication
Submitted
12 Jul 2000
Accepted
29 Aug 2000
First published
20 Sep 2000

Chem. Commun., 2000, 1925-1926

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A one-step, enantioselective reduction of ethyl nicotinate to ethyl nipecotinate using a constrained, chiral, heterogeneous catalyst

S. A. Raynor, J. M. Thomas, R. Raja, B. F. G. Johnson, R. G. Bell and M. D. Mantle, Chem. Commun., 2000, 1925 DOI: 10.1039/B005689H

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