Issue 16, 2000
From the journal:

Chemical Communications

Insertion of O2 into a Pd(i)–Pd(i) dimer and subsequent C–O bond formation by activation of a C–H bond

Víctor Durà-Vilà,a   D. Michael P. Mingos,a   Ramón Vilar,*a   Andrew J. P. Whitea  and  David J. Williamsa  

* Corresponding authors

a Department of Chemistry, Imperial College, London, UK
E-mail: r.vilar@ic.ac.uk

Abstract

The reaction between O2 and the dimer [Pd2(μ-Br)2(PBut3)2 ] leads to the formation of the novel dimeric compound [[upper bond 1 start]Pd(μ-OCH2{CMe2}P[upper bond 1 end]Bu t2)Br]2 by coordination of O2 to the original palladium dimer and further formation of two C–O bonds by intramolecular activation of C–H bonds.

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Article information

DOI
https://doi.org/10.1039/B004537N
Article type
Communication
Submitted
07 Jun 2000
Accepted
10 Jul 2000
First published
26 Jul 2000

Chem. Commun., 2000, 1525-1526

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Insertion of O2 into a Pd(I)–Pd(I) dimer and subsequent C–O bond formation by activation of a C–H bond

V. Durà-Vilà, D. M. P. Mingos, R. Vilar, A. J. P. White and D. J. Williams, Chem. Commun., 2000, 1525 DOI: 10.1039/B004537N

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