Issue 17, 2000

Michael addition of N-bonded enolato ligands to acrylonitrile in iron and ruthenium complexesElectronic supplementary information (ESI) available: physical and spectroscopic data for 1a and 1b. See http://www.rsc.org/suppdata/cc/b0/b004099l/

Abstract

Treatment of the N-bonded enolatoiron(II) complex [M(H)(NCCHCO2R)(L)2] [1a, M = Fe, R = Me, L = depe {1,2-bis(diethylphosphino)ethane}; 1b, M = Fe, R = Et, L = depe; 2, M = Ru, L = dppe] with acrylonitrile results in mono-Michael addition to give [M(H){NCC(C2H4CN)CO2R}(L)2 ], which is found to be an active intermediate for the catalytic double-Michael reaction of cyanoacetate with acrylonitrile.

Supplementary files

Article information

Article type
Communication
Submitted
22 May 2000
Accepted
26 Jul 2000
First published
23 Aug 2000

Chem. Commun., 2000, 1679-1680

Michael addition of N-bonded enolato ligands to acrylonitrile in iron and ruthenium complexes

M. Hirano, S. Kiyota, M. Imoto and S. Komiya, Chem. Commun., 2000, 1679 DOI: 10.1039/B004099L

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