Issue 14, 2000
From the journal:

Chemical Communications

Phosphodiester bond cleavage mediated by a cyclic β-sheet peptide-based dinuclear zinc(ii) complex

Keiichi Yamada,†a   Yu-ichi Takahashi,a   Hatsuo Yamamura,a   Shuki Araki,a   Kazuki Saitob  and  Masao Kawai*a  

* Corresponding authors

a Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, Japan.
E-mail: kawai@ach.nitech.ac.jp

b Yokoyama CytoLogic Project, ERATO, Japan Science and Technology Corporation, Tsukuba, Japan

Abstract

A dinuclear Zn(II) complex of N2δ,N2δ,N 2′δ,N2′δ-tetra kis(2-pyridylmethyl) derivative of cyclic peptide gramicidin S markedly accelerated the cleavage of the phosphodiester linkage of the RNA model substrate 2-hydroxypropyl p-nitrophenyl phosphate.

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Article information

DOI
https://doi.org/10.1039/B003370G
Article type
Communication
Submitted
26 Apr 2000
Accepted
05 Jun 2000
First published
28 Jun 2000

Chem. Commun., 2000, 1315-1316

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Phosphodiester bond cleavage mediated by a cyclic β-sheet peptide-based dinuclear zinc(II) complex

K. Yamada, Y. Takahashi, H. Yamamura, S. Araki, K. Saito and M. Kawai, Chem. Commun., 2000, 1315 DOI: 10.1039/B003370G

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