Substituted vinyl ethers carrying electron-donating groups in the ether moiety undergo smooth oxygen to carbon rearrangement with triisobutylaluminium to afford chain extended alcohols.
Triisobutylaluminium promoted reductive rearrangement of substituted vinyl ethers to homologous alcohols
B. du Roizel, M. Sollogoub, A. J. Pearce and P. Sinaÿ, Chem. Commun., 2000, 1507 DOI: 10.1039/B003277H
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