The first organoruthenium(IV) complexescontaining nitrogen donor ligands by oxidative addition of allylicsubstrates to coordinatively unsaturated Ru(II)complexes

Hideo Kondo; Yoshitaka Yamaguchi; Hideo Nagashima

doi:10.1039/B002927K

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The first organoruthenium(iv) complexes containing nitrogen donor ligands by oxidative addition of allylic substrates to coordinatively unsaturated Ru(ii) complexesElectronic supplementary information (ESI) available: typical procedures and spectroscopic data. See http://www.rsc.org/suppdata/cc/b0/b002927k/

Hideo Kondo,^a Yoshitaka Yamaguchi^a and Hideo Nagashima*^a

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* Corresponding authors

^a Institute of Advanced Material Study, Kyushu University, Kasuga, Fukuoka, Japan, Japan.
E-mail: nagasima@cm.kyushu-u.ac.jp

Abstract

Oxidative addition of allylic substrates to coordinatively unsaturated ruthenium(II), (η⁵-C₅Me₅)Ru(amidinate) complexes, afford cationic ruthenium(IV) compounds, [(η⁵-C₅Me₅)Ru(amidinate)(η³-allyl)]⁺, which have been characterized by spectroscopic analysis and X-ray structure determination.

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Article information

DOI: https://doi.org/10.1039/B002927K
Article type: Communication
Submitted: 12 Apr 2000
Accepted: 08 May 2000
First published: 31 May 2000

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Chem. Commun., 2000, 1075-1076

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The first organoruthenium(IV) complexes containing nitrogen donor ligands by oxidative addition of allylic substrates to coordinatively unsaturated Ru(II) complexes

H. Kondo, Y. Yamaguchi and H. Nagashima, Chem. Commun., 2000, 1075 DOI: 10.1039/B002927K

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