Issue 17, 2000
From the journal:

Chemical Communications

Oxidation of [(cyclic triamine)(1,5-cyclooctadiene)iridium]+ cations by hydrogen peroxide forms metallaoxetanes

Thomas C. Flood,*a   Masanori Iimura,a   Jeremy M. Perotti,a   Arnold L. Rheingoldb  and  Thomas E. Concolinob  

* Corresponding authors

a Department of Chemistry, University of Southern California, Los Angeles, CA, USA.
E-mail: flood@chem1.usc.edu

b Department of Chemistry and Biochemistry, University of Delaware, Newark, DE, USA

Abstract

Iridaoxetane 3 formed by oxidation of 1 with aqueous H2O2 is isolated and characterized, providing a rare example of formation of a metallaoxetane by direct oxidation of a metal–alkene complex.

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Article information

DOI
https://doi.org/10.1039/B002079F
Article type
Communication
Submitted
08 Mar 2000
Accepted
20 Jul 2000
First published
23 Aug 2000

Chem. Commun., 2000, 1681-1682

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Oxidation of [(cyclic triamine)(1,5-cyclooctadiene)iridium]+ cations by hydrogen peroxide forms metallaoxetanes

T. C. Flood, M. Iimura, J. M. Perotti, A. L. Rheingold and T. E. Concolino, Chem. Commun., 2000, 1681 DOI: 10.1039/B002079F

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