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Issue 10, 2000
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Configurationally stable metal-centered chirality:stereospecific and regioselective rhodaacylation of alkynes controlled bythe third generation of the [Cp′-P]H ligand

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The rhodium cationic complex [[η5∶η1-{3-(NIM)Ind-P} n = 2]Rh(CO)Me]BF4 (1) reacts with 1-phenylpropyne regioselectively and stereospecifically to afford the alkenyl complex [[η5∶η1-{3-(NIM)Ind-P} n = 2]Rh{η2-O[double bond, length half m-dash]C(CH3)- C(CH3)[double bond, length half m-dash]CPh}]BF4 (2).

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The article was received on 03 Mar 2000, accepted on 07 Apr 2000 and first published on 03 May 2000

Article type: Communication
DOI: 10.1039/B001735N
Citation: Chem. Commun., 2000,0, 841-842

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    Configurationally stable metal-centered chirality: stereospecific and regioselective rhodaacylation of alkynes controlled by the third generation of the [Cp′-P]H ligand

    Y. Kataoka, Y. Iwato, A. Shibahara, T. Yamagata and K. Tani, Chem. Commun., 2000, 0, 841
    DOI: 10.1039/B001735N

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