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Issue 8, 2000
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Palladium–indium mediated Barbier-type allylation of aldehydes with allenes

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Abstract

A new allylation reaction of carbonyl compounds using allenes is described; homoallylic alcohols were obtained in moderate to good yields from aryl iodides, allenes and carbonyl compounds and an excellent diastereoselection was exhibited when 2-hydroxycyclohexanone was employed.

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Article information


Submitted
22 Feb 2000
Accepted
06 Mar 2000
First published
27 Mar 2000

Chem. Commun., 2000, 645-646
Article type
Communication

Palladium–indium mediated Barbier-type allylation of aldehydes with allenes

U. Anwar, R. Grigg, M. Rasparini, V. Savic and V. Sridharan, Chem. Commun., 2000, 645
DOI: 10.1039/B001457P

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