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Issue 12, 2000
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Formation of a diphosphine: synthesis and molecular structure of bis(tetraphenylbutadienyl)diphosphine, (Ph4C4)P–P(C4Ph4)

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Abstract

Reaction of 1,4-dilithiotetraphenylbutadiene with phosphorus(III) bromide affords bis(tetraphenylbutadienyl)diphosphine, (Ph4C4)P–P(C4Ph4), with a phosphorus–phosphorus bond length of 2.2051(11) Å.

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Article information


Submitted
14 Feb 2000
Accepted
05 Apr 2000
First published
25 May 2000

Chem. Commun., 2000, 1037-1038
Article type
Communication

Formation of a diphosphine: synthesis and molecular structure of bis(tetraphenylbutadienyl)diphosphine, (Ph4C4)P–P(C4Ph4)

J. K. Vohs, P. Wei, J. Su, B. C. Beck, S. D. Goodwin and G. H. Robinson, Chem. Commun., 2000, 1037
DOI: 10.1039/B001257M

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