Facile dynamical intramolecular exchange of a phosphine ligand between two different metal atomsElectronic supplementary information (ESI) available: experimental section. See http://www.rsc.org/suppdata/cc/b0/b001080o/
Abstract
The cluster complex PtRu5(CO)15(PMe2Ph)(μ6-C) has been shown to exhibit facile intramolecular exchange of the phosphine ligand between a platinum and ruthenium atom that is rapid on the NMR timescale at 160 °C.