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Issue 10, 2000
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Synthesis and molecular structure of the unsymmetrically substituted magnesium alkyl Mg(Bun){CH[SPh][SiPh2(CH 2NC5H10)]}

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Abstract

The unsymmetrically substituted magnesium alkyl Mg(Bun){CH[SPh][SiPh2(CH 2NC5H10)]} (NC5H10 = 1-piperidyl) with a stereogenic metalated carbon atom is obtained by deprotonation of an (aminomethyl)[(phenylthio)methyl]silane with MgBunBus and examined by single crystal X-ray diffraction analysis and theoretical methods.

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Article information


Submitted
12 Jan 2000
Accepted
10 Apr 2000
First published
05 May 2000

Chem. Commun., 2000, 865-866
Article type
Communication

Synthesis and molecular structure of the unsymmetrically substituted magnesium alkyl Mg(Bun){CH[SPh][SiPh2(CH 2NC5H10)]}

C. Strohmann, B. C. Abele, D. Schildbach and K. Strohfeldt, Chem. Commun., 2000, 865
DOI: 10.1039/B000494O

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