By employing dibromo or diiodomethane as halomethyllithium precursors, the in situ double and triple homologation of boronate esters has been obtained for the first time.
Homologations of boronate esters: the first observation of sequential insertions
L. Ren and C. M. Crudden, Chem. Commun., 2000, 721 DOI: 10.1039/B000243G
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