Issue 15, 2000
From the journal:

Chemical Communications

Oxygen initiated unprecedented condensation of propargylamine into the 1,3-di(propargylimino)propylateanion coordinated to cobalt(iii)

Aleksei A. Sidorov,a   Marina O. Ponina,a   Sergei M. Deomidov,a   Vladimir M. Novotortsev,a   Albert Demonceau,b   Sergei E. Nefedov,a   Igor L. Eremenko*a  and  Ilya I. Moiseeva  

* Corresponding authors

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, GSP-1, Leninsky prosp., Moscow, Russia.
E-mail: ilerem@ionchran.rinet.ru

b Laboratory of Macromolecular Chemistry and Organic Catalysis, C.E.R.M. University of Liege, Liege, Belgium

Abstract

Condensation of coordinated propargylamine into the unprecedented 1,3-di(propargylimino)propylateanion, an analogue of the acetylacetonate anion, is initiated by dioxygen in the Co(II) polymeric trimethylacetate complex/NH2CH2C[triple bond, length half m-dash]CH system; molecular structures of the intermediate complex, Co(O2CCMe3)2(H2NCH2 C[triple bond, length half m-dash]CH)4 and final product Co(O2CCMe3)2(NH2CH2 C[triple bond, length half m-dash]CH)2[N,N′-(HC[triple bond, length half m-dash]CCH 2NCHCHCHNCH2C[triple bond, length half m-dash]CH)] were established by X-ray analysis.

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Article information

DOI
https://doi.org/10.1039/B000004N
Article type
Communication
Submitted
04 Jan 2000
Accepted
23 May 2000
First published
05 Jul 2000

Chem. Commun., 2000, 1383-1383

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Oxygen initiated unprecedented condensation of propargylamine into the 1,3-di(propargylimino)propylateanion coordinated to cobalt(III)

A. A. Sidorov, M. O. Ponina, S. M. Deomidov, V. M. Novotortsev, A. Demonceau, S. E. Nefedov, I. L. Eremenko and I. I. Moiseev, Chem. Commun., 2000, 1383 DOI: 10.1039/B000004N

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