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Issue 7, 2000
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The dinuclear manganese complex Mn2O(OAc)2(TPTN) as a catalyst for epoxidations with hydrogen peroxideAbbreviations TPTN = N,N,N′,N′-tetrakis(2-pyridylmethyl)propane-1 ,3-diamine, TPEN = N,N,N′,N′-tetrakis(2-pyridylmethyl)ethane-1, 2-diamine.

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Abstract

In acetone and at ambient temperature, the dinuclear manganese complex of TPTN is able to catalyse the oxidation of several alkenes to the corresponding epoxides with high turnovers numbers (up to 900) using H2O2 as oxidant.

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Article information


Submitted
17 Dec 1999
Accepted
24 Feb 2000
First published
15 Mar 2000

Chem. Commun., 2000, 537-538
Article type
Communication

The dinuclear manganese complex Mn2O(OAc)2(TPTN) as a catalyst for epoxidations with hydrogen peroxide

J. Brinksma, R. Hage, J. Kerschner and B. L. Feringa, Chem. Commun., 2000, 537
DOI: 10.1039/A910232I

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